Single Molecule Magnets and Single Chain Magnets Analysis

Single Molecule Magnets and Single Chain Magnets Analysis The structures and attractive properties: sub-atomic nanomagnets phenolic oxime edifices GUAN Shengyang Chapter by chapter list (Jump to) 1 Introduction 1.1 Research foundation 1.2 Introduction to nanomagnets 1.2.1 Single particle magnet 1.2.2 Single Chain magnet (attractive nanowires) 1.3 Structure of phenolic oxime and edifices 2 Researches 2.1 Iron complex 2.2 Manganese edifices 2.3 Complex containing cobalt and sodium particles 2.4 Complex containing lanthanide 3 Conclusion 4 Bibliography Unique The fundamental ideas expected to comprehend and show singlechain magnets will likewise be explored. 1 Introduction 1.1 Research foundation The investigates on sub-atomic nanomagnets started from 1990s, when the main single particle magnet (SMM) [Mn12O12(O2CPh)16(H2O)4 was explored by Christougroup of University of Florida. [GS1]This blended valent manganese complex was found to have an anomalous high turn ground province of S=10[GS2] and most elevated blocking temperature (underneath which temperature could the nanomagnets show attractive properties) in its family ([Mn12O12(O2CR)16(H2O)4], R = different). An enormous number of SMMs have been accounted for from that point forward. These[GS3] sort of buildings show the traditional property of charge hysteresis[GS4] and quantum properties of quantum burrowing of the polarization (QTM). These underlying disclosures give a sub-atomic way to deal with nano-scale attraction. Following examination of single particle magnets (SMMs) and single chain magnets (SCMs) voyagers their possible applications in high-thickness data storage[GS5], quantum computing[GS6], attractive refrigeration [GS7]and so on. Be that as it may, until this point in time, nanomagnets found have low blocking temperature (TB). So it is critical to pick fitting chelate ligands and comparing metal focuses to develop an appropriate complex with properties to improve blocking temperature (TB) for functional application. Phenolic oxime is a group of mixes with nonexclusive structure appeared in Figure 1. The phenolate and oxime work gatherings could shape intramolecular hydrogen holding with its neighbor. These hydrogen holding bringing about solid coordination impact on metal particles. Such property makes phenolic oxime a decent extractant for copper[GS8] in mining industry. Point by point conversation of the phenolic oxime complex structure will be presented in SECTION 1.3 . Figure 1 general structure of phenolic oxime In this survey, information on nanomagnets will be acquainted initially with give an outline of this field. At that point the structure and attractive properties of mixes with phenolic oxime ligand will be presented. New procedures applied in union will likewise be incorporated. It is trusted that this audit could be utilized to evaluate the capability of phenolic oxime ligand in elite nanomagnets. 1.2 Introduction to nanomagnets 1.2.1 Single particle magnet It is useful to depict the essential hypothesis of SMM with a model. The primary single particle magnet (SMM) [Mn12O12(O2CCH3 )16(H2O) 4] 4H2O ·2CH3CO2H[GS9] was resolved to have a S=10 ground turn state, which is contributed by the antiferromagnetic associations between 4 MnIV particles and 8 MnIII ions[GS10]. Dislike typical size magnet, SMM shows moderate attractive unwinding underneath a trademark blocking temperature. This wonder is clarified by the exist of a vitality boundary in reorientation procedure of attractive second. Sessoli et.al. affirmed there exists a generally enormous zero-field parting in this particle by high-field EPR explores different avenues regarding a CO2 far-infrared laser. This hub zero-field parting prompts a parting of the S=10 state into 21 levels: - 10 , - 9 , - 8, - 7, - 6 , - 5†¦0, 1, 2, 3†¦8, 9, 10. Each level is portrayed by a turn projection quantum number ms, comparing likely vitality: †¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦ †¦..(1) D:axial zero-field parting boundary. In [Mn12O12(O2CCH3 )16(H2O) 4] 4H2O ·2CH3CO2H D=-0.5cm-1 Figure 2 Figure 1. PovRay portrayal of the center of[Mn12O12(O2CCH3 )16(H2O) 4] 4H2O ·2CH3CO2H, indicating the overall places of the MnIV particles (concealed circles), MnIII particles (strong circles), and  µ3-O2 spans (open circles[GS11]). Figure 3: Plot of expected vitality of various turn state versus polarization bearing From Figure 3, it could be realized that the parting of potential vitality levels bringing about a potential vitality boundary during the time spent changing the attractive second. For the model SMM, this obstruction equivalents to E(ms=0)- E(ms=à ¢Ã¢â‚¬ Ã¢â‚¬Å¡Ã‚ ±10à ¢Ã¢â‚¬ Ã¢â‚¬Å¡)=100D. Because of the little estimation of D, this hindrance could be handily crossed in room temperature. In the event that example SMM is polarized at 1.5K, the attractive unwinding time turns out to be too long to even consider measuring. At the point when fitted into Arrhenius relationship: †¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦.†¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦Ã¢â‚¬ ¦(2) The attractive anisotropy of the SMM is brought about by the structure of the eight MnIII particles. Each MnIII particle with in octahedral gem shows Jahnâ€Teller bending. These distortion[GS12] along with turn orbital connection offer ascent to the simple pivot kind of magnetoanisotropy. To finish up, an average SMM comprises of an inward attractive center with an encompassing shell of natural ligands. The ideal SMM requires very much detached framework which display high turn ground state (S) with a high attractive anisotropy of the simple pivot (Ising) type. The trouble is: high turn ground state frequently demands for a few cores, yet the attractive direction of every cores will in general comply with Maximum Entropy Models. Along these lines, the most noteworthy magnetoanisotropy of a particle couldn’t be accomplished without any problem. A few investigates show that supplanting attractive center with lanthanide[GS13] particles or utilizing single nuclearity spincluster [GS14]could keep away from this issue. Their methodologies will be talked about in SECTION 2. 1.2.2 Single Chain magnet (attractive nanowires) While groups of SMM can be considered as zero dimensional material, it is conceivable that one dimensional materials, for example, nanowires display moderate attractive unwinding and hysteresis impacts which are not related with three-dimensional (3D) request. At 1963, Glauber[GS15] anticipated one measurement Ising model (simple pivotal) would show charge unwinding under low temperature. Because of deficient information around there and rigid conditions required in the amalgamation method, scientific expert wasn’t have the option to discover any confirmations to help or against the forecast, until Gatteschi et al effectively union [Co(hfac)2(NITPhOMe[GS16])] in 2001. Figure 4 Structure of NITPhOMe=4†²-methoxy-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide Figure 5 Drawing of unit cell of[Co(hfac)2(NITPhOMe)2]. Huge dull circles speak to the metal particles. Hydrogen, fluorine, and a large portion of the methyl carbon particles have been precluded for clearness The structure of the SCM comprises of Co(hfac)2 and radicals orchestrated in helices then again( Figure 5). In this one dimensional structure, the attractive center (octahedral cobalt(II) focuses) has generally speaking S=1/2 and shows simple hub of polarization in the chain direction[SG17]. Nitty gritty investigation of ranges could be found in Caneschi’s report in 2001. To finish up, three fundamental conditions are requirement for structure SCMs: 1) the proportion of the collaboration and connections is huge. 2) the material must carry on as a 1D Ising ferro-or ferrimagnet. This requires the structure square or the center of the chain have enormous ground state turn. 3) the interchain connections ought to be limited to keep away from the attraction of the material be related with three-dimensional (3D) request. This last condition likewise apply for SMMs. 1.3 Structure of phenolic oxime and buildings Metal buildings with a planar, electronically delocalized structure have demonstrated especially alluring for improvement of helpful electronic properties in light of the solid moleculeâ€molecule communications that can emerge from Ï€-stacking of the planar units 2 Researches 2.1 3d nanomagnet Numerous 3d nanomagnets have been orchestrated and explored on since the first SMM was found. f hexanuclear MnIII SMMs dependent on the complex [MnIII6O2(sao)6(O2CH)2(EtOH)4](saoH2=salicylaldoxime[GS18])9-12 Turn Switching by means of Targeted Structural Distortion 2.2 Iron complex Variety of alkyl bunches on the ligand fromt-octyl ton-propyl empowered electronic disengagement of the buildings in the gem structures of M(L1)2contrasting with Ï€-stacking cooperations for M(L2)2(M = Ni, Cu). This was confirm by a one-dimensional antiferromagnetic chain for Cu(L2)2but perfect paramagnetic conduct for Cu(L1)2down to 1.8 K. 2.3 Complex containing cobalt and sodium particles 2.4 Complex containing lanthanide Albeit numerous attractive change metal buildings have been combined, the temperature required for progress metal complex to show polarization unwinding (for example blocking temperature) is excessively low. Consequently lanthanide metals were acquainted with the complex to expand the blocking temperature. 4 Bibliography [GS1]R. Sessoli, H.- L. Tsai, A.R. Schake, S. Wang, J.B. Vincent, K. Folting, D. Gatteschi, G. Christou,â and D.N. Hendrickson, J. Am. Chem. Soc. 115â (1993) p. 1804. Sessoli, R.; Tsai, H.- L.; Schake, A.R.; Wang, S.; Vincent, J.B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D.N.J. Am. Chem. Soc.1993, 115, 1804-1816. [GS2]à ¥Ã‚ Ã…'à ¤Ã‚ ¸Ã… à ¦-†¡ [GS3]Resonant charge burrowing in the half-number turn single-atom magnet [PPh4][Mn12O1

Philosophy Assignment Example | Topics and Well Written Essays - 750 words - 10

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3 Simple Tips To Market Your Blog Or Website

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Chevron Corporation Free Essay Example, 2000 words

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Canterbury Tales Essay Prompts Example For Students

Canterbury Tales Essay Prompts Canterbury TalesCharacter AnalysisChaucers greatest work came after everything else. Canterbury tales was the last of his literary works. It followed such stories as Troilus and Creseyde. It is considered as one of the greatest works of literature during the English Middle Age. The ironic thing is that it wasnt even finished the way Chaucer had intended it to. He had planned to have over a hundred tales, four for each pilgrim. He ended up with twenty-four, less than one for each pilgrim. One wonders if he had finished how much better would it have been. The story is a unique one, especially during the time in which it was written. Rather than a traditional author story format, Chaucer uses a different method to spin a number of different types of stories. By telling different stories through different pilgrims Chaucer uses their attitudes and characteristics so that he may tell tales of many different varieties and styles. This shows the many different creative sides and motives of the great author. He was not the first to use such a method, but he may be one of the most famous, earliest of its users. Among the number of characters and different storytellers you come across a character by the name of Robin. His standing among the company was the Miller, so that was what he would be more commonly known. Immediately following the Knight the Miller had a pretty tough act to follow. The Knight was obviously of high standing, and would previously tell a noble tale with a moralistic flavor to it. It would leave the crowd in state of appreciation for someone of his stature. When his tale was done the people knew why it was that he was Knight. Although, when the Miller was done the people did also realize why he was the Miller. When the Knights tale had finished the Miller decided it was his turn for the spotlight. Chaucer makes it quite easy to understand the contrast in the characters. Especially making the claims one right after the other. The comparison is easily made. The drunken boisterous Miller pipes up claiming to have a tale that would contend with the Knights for being noble and attractive. Sensing the drunkenness, the host speaks up telling the Miller to save his tale for another time knowing of what was to come. The loud and cocky Miller overpowers him. He states that his tale is one of infidelity between a carpenter and his wife. The narrator even tries to apologize for the following drunken blabbering. The stage had pretty much been set. In short, the tale is of a carpenter and his wife. Being very busy with business the carpenter is not around much and eventually his wife would be seduced by a man of a lower social standing than her husband by the name of Nicholas. She also would be sought after by a guitar-playing luster, who for the times would have been more suitable for an adulterous escapade. His name was Absolom. She would trick her husband into distraction so that she may sleep with Nicholas, all the while teasing and insulting Absolom with cruel and somewhat disgusting technique. In the end, each man had been punished, the carpenter was thought to be crazy by the townspeople and had been injured in a fall, Nicholas would be burned by Absolom, and Absolom himself would be humiliated for his troubles. The tale for the most part had left the people in a state of shock. They were aghast after hearing a story as good as the Knights and then having to sit through the Millers attempt at entertainment. There is a name for this type of childish grotesque tale however. It is called fabliau it is a familiar medieval literary that would concern the more vulgar classes during its display. Since it had followed the Knights tale and had made a mockery of it, the Miller had managed to bring down the tale and strip it of its pride and morale.After hearing the Knights tale and seeing the peoples reaction to it I think the Miller became a little jealous and decided that he should be in

Great Essays (2054 words) - The Great Gatsby, Jay Gatsby

Great Gatsby Themes In The Great Gatsby, by F. Scott Fitzgerald, many themes are enclosed; the most salient of these themes is related to the American Dream. The American Dream is based on the idea that any person, no matter what they are, can become successful in life by his or her hard work. The dream also embodies the idea of a self-sufficient person, an entrepreneur making it successful for themselves. The Great Gatsby is about what happened to the American Dream during the 1920s, an era when the dream had been corrupted by the relentless pursuit of wealth. In this novel, the pursuit of the American Dream and the pursuit of a romantic dream are the ultimate causes of the downfall of the book's title character, Jay Gatsby. Throughout the story, Jay Gatsby avoids telling the truth of his hard, unglamorous childhood. He does this to keep his superficial image of himself and to save himself from the embarrassment of being in a state of poverty during his youth. His parents were lazy and unsuccessful people who worked on the farm, and because of this Gatsby never really accepted them as his parents. Jay Gatsby's real name is James Gatz and he is from the very unexciting North Dakota. He changed his name to Jay Gatsby when he was seventeen years old, which was the beginning of his version of the American Dream. In all realities Gatsby arose from his Platonic view of himself, the idealistic self-view that a seventeen year old boy has of himself (Fitzgerald 104). Though concealed for most of the story, Gatsby's embarrassing childhood is a major source of determination in his attempt to achieve the American Dream. During Gatsby's early adulthood, he joined the army. He first met Daisy when he was at Camp Taylor and he and some other officers stopped by her house. He initially loved Daisy because of her extraordinary house and because many other men had been with her already. One evening in October, during 1917, Gatsby fell in love with Daisy Fay, and in turn she fell in love with Gatsby. "Daisy was the first ?nice' girl that he had ever known" (Fitzgerald 155). Their love was an uneasy one at first for Gatsby to comprehend because he wasn't rich by any standards and he felt that he wasn't worthy of Daisy's affection, but his uneasiness was uplifted when he and Daisy fell in love and when he found out that Daisy knew a lot because he knew a variety of things that she didn't. Their month of love was physically ended when Gatsby had to go to war, but their emotional love never ended. As Gatsby performed brilliantly throughout the war, they wrote each other frequently. Daisy couldn't understand why Gatsby couldn't come home. She wanted her love to be their with her, she needed some assurance that she was doing the right thing. It didn't take long for Daisy to get over Jay because in the Spring of 1918 she fell in love with a rich, former All-American college football player named Tom Buchanon. This broke Jay Gatsby's heart. His love for Daisy was a strong one and he was determined to get her back. This first love with Daisy had a great impact on his idea of one of the aspects of achieving the American Dream. Throughout the novel, the reader is mislead about how Gatsby became wealthy. Gatsby claims on several different occasions that he inherited his parents' immense fortune. This is a story that Gatsby made up in order to keep his self-image up by not letting people know about his childhood. The truth is that Gatsby got rich by illegal measures. He was friends with the notorious Meyer Wolfsheim. Meyer Wolfsheim was the racketeer who supposedly fixed the World Series of 1919. He was Gatsby's connection to organized crime, in which Gatsby became rich. Gatsby's true sources to richness were selling bootleg liquor in his chain of drug stores and creating a giant business to get rid of and sell stolen Liberty bonds (Mizener 188). Gatsby's methods of gaining wealth corrupt the morality of the American Dream although they help him to achieve it. It did not take long for Gatsby to attempt to win Daisy back after he returned from the army. Jay Gatsby had this romantic view of Daisy and himself together and happy forever. He felt the best way to achieve this idea would be for him to become at least as rich as Daisy's husband Tom Buchanon.

3 Errors Involving Prepositions

3 Errors Involving Prepositions 3 Errors Involving Prepositions 3 Errors Involving Prepositions By Mark Nichol You are attempting to describe an action, but you can’t remember whether one, say, goes in to the breach or into the breach, or whether one, for example, walks on to the next trail junction or onto the next trail junction. This post explains the respective roles of the operative words and phrases. A prepositional phrase is a phrase that includes a preposition, a word that, as its name implies, comes before the object of a sentence. For example, into and onto are prepositions describing movement in relation to objects in the prepositional phrases â€Å"into the trench† and â€Å"onto the roof.† Because these prepositional phrases provide additional information about an action that occurred (as in the sentences â€Å"She leaped into the trench† and â€Å"The boy climbed onto the roof†), they serve as adverbs. We usually think of adverbs as single words (as in â€Å"She leaped impetuously† or â€Å"The boy climbed quickly†), but adverbs can consist of two or more words, which appear without any additional information or combined with one-word adverbs, either adjacent to each other or separated by the subject and the verb (as in â€Å"She leaped impetuously into the trench† or â€Å"Quickly, the boy climbed onto the roof†). â€Å"In to† and â€Å"on to,† by contrast, each contain two distinct parts of speech: an adverb followed by a preposition. In and on follow a verb to provide additional information about it, and to precedes the object that follows the verb and its adverb, as in â€Å"She leaped in to search the trench† and â€Å"The boy climbed on to get a better look.† In the following examples, a preposition is mistakenly employed in place of an adverb-preposition compound consisting of the same letters as the preposition. After each sentence, a discussion, followed by a revision, explains the error. 1. His wife, under the assumption that she’d never see him again, has moved onto another man, and they’re planning on getting married. The prepositional phrase â€Å"moved onto† implies that the woman has literally relocated herself on the man’s body. However, â€Å"moved on to† includes the idiomatic phrase â€Å"moved on,† meaning â€Å"transitioned†: â€Å"His wife, under the assumption that she’d never see him again, has moved on to another man, and they’re planning on getting married.† 2. His job is not to give into the demands of multimillionaire celebrities pushing a social agenda. The use of into implies an entrance, but the key of this sentence is the idiom â€Å"give in,† meaning â€Å"submit,† so into must be broken up into its constituent parts: â€Å"His job is not to give in to the demands of multimillionaire celebrities pushing a social agenda.† 3. The cell phones were turned into the authorities. Here, into preceded by turned suggests a transformation, rather than the act of turning in, or handing over, so again, in must be separated from to to form part of the phrase â€Å"turning in†: â€Å"The cell phones were turned in to the authorities.† For a more detailed discussion about this issue, see this post about prepositions. Want to improve your English in five minutes a day? Get a subscription and start receiving our writing tips and exercises daily! Keep learning! Browse the Grammar category, check our popular posts, or choose a related post below:Coordinating vs. Subordinating Conjunctions75 Idioms and Expressions That Include â€Å"Break†Oppose and Opposed To

Shareholders Value Essay Example | Topics and Well Written Essays - 1500 words

Shareholders Value - Essay Example The entries are counterbalanced so that the assets always equal the liabilities and owner's equity. The balance sheets of the company are examined by shareholders. The fundamental principles of economics are optimization and market equilibrium. The optimization principle says that people choose the best consumption patterns that they can afford. The market equilibrium principle states that prices adjust till demand equals supply. A supply curve measures how much of a good will be supplied at a given price. Suppose we reach a price p for the supply of a quantity x. The producer would be willing to supply a smaller amount at a lower price. However the entire quantity is sold at the price p. The producer's surplus measures the gains to the firm by selling all the goods at the higher price p. The concept of surplus enables us to determine the gains and losses for the firm. The consumer's surplus is the difference between the gross benefit of consuming the good and the price paid for that good. This perspective lets us understand the firm from economics theory. The concept of producer's surplus is closely linked to the concept of profit. 9. The accounting approach does not measure the large gaps between the true value of the firm and the observed market value. The economics perspective considers all the variables that influence the market till we find a match between the actual and the calculated market values of a firm. 10. Shareholders in a firm rely on accounting practices more that economic calculations because accounting numbers are easily available for analysis. 11. Every accounting decision has an economic consequence while the changes in the economic picture are not necessarily reflected in accounting. 12. While accounting is a simple process based on conventions and numbers available with the firm, economic considerations are very complex and involve many variables. The values of economic variables are not readily available and are many times external to the firm. 13. While accounting is by nature a short term activity, economic analysis is a long term activity. 14. Accounting has methods in place for auditing the firm. Economic methods do not have established audit procedures in place. 15. While accounting

Questions & answers Assignment Example | Topics and Well Written Essays - 500 words

Questions & answers - Assignment Example As the CMO, Dr. Yeasted is on the finance body making suggestions and approvals for any budgeting to be carried out. In his role, he has to prioritize issues in order for the most important and necessary at the moment to take precedence in the budget and also have to explain the same to the staff. The strategic plan at the moment in the hospital is that of trying to streamline the hospital activities and quality with the new health care policies such as the managed care and affordable care act. This is still what he worked on and the success is starting to be evident. Prior to him becoming a CMO, Dr. Yeasted was a Board member of the same hospital and hence has a cordial relationship with the board members including the chairman. This relationship is free of tension as they have known each other for long and have also worked together as physicians. The most enjoyable thing is that he gets to change the life of the community by simply making the correct decisions and implementation of the policies which is part of his job as a CMO. The least enjoyable is attending and participating in meetings which take up majority of his time (Kassel, 2015). I was surprised that the CMO had many roles up their sleeves and sometimes even did not find to practice medicine. I thought their life was just easy as there were other administrators and the Board in the hospital and hence he only had to do the approving and nothing else. According to Dr. Yeasted, in as much a health care administrator is busy with office work and meetings, he or she needs to set aside side time to visit the patients and interact on an informal basis with the staff to not only create rapport but learn more about the hospital. The CMO advices the students who wish to become administrators to become conversant with the issues of finance and take precaution about it. The finances are different from other organizations and hence need different strategies to handle them as well as know how to

Press Release Order Essay Example for Free

Press Release Order Essay The demand for International translation services has been constantly increasing for the past few years. Moreover, the growing number of Internet users every year has resulted into a similar and broader demand which is online translation. Basically, it is clear that these days, clients all over the world need quick and reliable technical translation services that they can easily access using the Internet. As a response to these demands, a leading translation company has recently expanded its business operation and has recruited professional translators who can fully meet the translation needs of clients from all around the globe. In a general meeting held last April 1st 2008, company Manager James Tate emphasized to the employees that the adequate staff replenishment in the company have made translation services more approachable. As Tate said in the meeting, â€Å"We are all human beings as well as our clients. Some of us question this fact because of enormous amount of orders, but it is unquestionable that our clients need permanent help and support, thus, we decide to help our support and translators’ teams in order to deliver effective services to our clients†. In the meeting, Tate further stated that the company’s current manpower that provides website translation service has constantly met the growing demands of clients in live support. According to Tate, the company is in the eventual expansive mode responding the world translation services, in which the company has grown and leading in both document translation service and foreign language translation. The manpower expansion of the company aims to deliver more professional translation services by adding twenty more high quality professional staff to double the translation capacities. Likewise, one of the important tasks in providing assistance to clients is the adequate maintenance of a live support. Tate believes that the live support is more significant in bringing about a personalized approach to clienteles and reaching out the services towards world translation. This kind of venture in international translation service has been a breakthrough of a reinvented industry using Internet technology. This venture operates like call center which is also a booming clientele-out-sourcing business. Likewise, the business in technical translation services is in the same league with other cyber technology innovations. In addition, some industrial technocrats perceive a looming demand in international translation services which may indicate vulnerability of competition, specifically by similar online business entities. One of the indications is the possible realignment of call centers into a one-stop-shop venture in business-process-outsourcing which may include technical translation services. This indication may not be a remote possibility reflective on the situation of the available technical manpower and academic professionals. Generally, the company’s online translation services would radiate a more definitive employment opportunity to absorb the people’s skills and potentials that are untapped by other industries and competing job markets. These skilled translators would then eventually become the cornerstone of a bigger and

Slaughterhouse-Five Essay: Irony, Dark Humor, and Satire :: Slaughterhouse-Five Essays

Irony, Dark Humor, and Satire in Slaughterhouse-Five Kurt Vonnegut uses a combination of dark humor and irony in Slaughterhouse-Five. As a result, the novel enables the reader to realize the horrors of war while simultaneously laughing at some of the absurd situations it can generate. Mostly, Vonnegut wants the reader to recognize the fact that one has to accept things as they happen because no one can change the inevitable. Although Slaughterhouse-Five may not be filled with delightful satire and comical scenes, there are accounts which the force the reader to laugh. In one instance, an extremely drunk Billy Pilgrim is searching desperately for the steering wheel of his car: "He was in the backseat of his car, which is why he couldn't find the steering wheel," Vonnegut writes (47). In another episode, Billy becomes "unstuck" in time while watching television, so that he sees a war film backwards and then forwards. The most humorous sequence takes place when Billy travels from the zoo on Tralfamadore to his wedding night with his wife, Valencia. He wakes up to find himself in the German prison camp. He then finds himself back with Valencia after returning from the bathroom. He goes to sleep, then wakes up on a train on the way to his father's funeral. In any case, the reader encounters much dark humor in the novel. There is a sense of an embittered humor with the Tralfamadorian phrase, "So it goes," which is repeated over 100 times in the novel. John May says that Vonnegut's purpose in repeating the phrase after each statement of death is to build its meaning with each incremental refrain (Contemporary Literary Criticism 8: 530). At first, the saying can be looked upon as funny in an ironic way. However, as one reads further, the phrase becomes irritating and irreverent. The reader cannot fathom so many deaths meaning so little. According t o Wayne McGinnis, it is most likely Vonnegut's intent to cause such feelings from the reader (Contemporary Literary Criticism 5: 468). This punctuating phrase forces the reader to look at the novel's deaths one after the other. Ultimately, the repetition creates a feeling of resentment that too many people are killed. The saying is a grim reminder that means exactly the opposite of what its words say. Vonnegut ends the novel with the reminder of the deaths of JFK, Martin Luther King, and all of those that died in Vietnam.

Addressing Inequality in the “Land of Opportunity”

The meaning or definition of what America is, was, or could become is the main subject that the two opposing voices relate in Langston Hughes’ poem Let America be America Again. Both voices acknowledge America is not the America that was envisioned by its founders/architects – i.e. a state built on the principles of freedom and equality, a land of opportunity for all. However, while the first voice simply calls for a recovery of the ideal America, the second voice, through articulations of the reality of social inequalities in America, argues for a reexamination of the said ideal, with the desired effect of making America  Ã‚   â€Å"The land that never has been yet–/And yet must be–the land where every man is free.† (lines 19-20) â€Å"Let America be America again† (line 1) , the first speaker begins. To him, America was a dream of dreamers, a â€Å"great strong land of love† (line 7), where â€Å"opportunity is real, and life is free/equality is in the air we breathe†. (line 13) He assertively states his notions of what America ought to be. However, he fails to identify what America has become instead. He also does not specify who the dreamers that dreamed America are, nor does he clarify who the â€Å"we† for whom equality. The choice of word â€Å"again† and the first speaker’s c onstant use of it suggest that to put America to its right direction, one needs to reacquaint the state to the glories it once had. However the assertion of the second speaker of America as the â€Å"never was† contrasts the difference of position of the two speakers. The second speaker contests the possibility that America had been the place where equality once reigned as he mumbles back to the first speaker that   Ã¢â‚¬Å"(There's never been equality for me/Nor freedom in this ‘homeland of the free.’) (lines 15-16) The disillusionment or discontentment in the tone of the second speaker who claims he is one of â€Å"the people† who built America challenges the first speaker’s idealization of America’s past. Also read: Was the American West a Land of Opportunity? The first speaker talks of freedom, equality for all but he/she could not even realize that there could be an opposition or challenge to his/her claims so he/she asks â€Å"Say, who are you that mumbles in the dark? /And who are you that draws your veil across the stars?† (lines 17-18) when he/she hears mumbles as he/she spoke. The first speaker addresses the person as if their existence were hardly thought of as he/she talked about America’s past and future. The second voice introduces himself: â€Å"I am† as the first voice is unable to recognize the second voice, who represents disenfranchised classes in America, the very reason America is not his ideal America, shows the first speaker's position in the society he seeks altered: he is an observer, not immersed in the reality of inequality and selective granting of rights, which the second voice knows first-hand.     Further on, he states that he (they) originated the dream of America. He briefly details America's founders – immigrants all, seeking escape from serfdom in the Old World, desiring a â€Å"home of the free’. According to the second voice, as America was founded by immigrants, and its industries and agriculture were built and maintained by laborers, these members of American society have a historically-supported claim to the freedom and equality deprived of them. The second speaker calls for a collective action of the people to rebuild America to be a place for the people, the dreamers who could call it â€Å"the land of the free† and not just for the few privileged people. The contesting ideas of the two voices/speakers in the poem about America stress that America as a country, as a word and even as a symbol for freedom and equality is a space of struggle between those who have the luxury to contemplate an abstract America and those who are immersed with the reality of how oppressive America is to the working classes and the ones with racial distinctions. To one, America is the dream of vague dreamers meant for an unspecified mass. To the other, America is a state built by people wishing to escape oppression in their nations of origin. America could not just be painted in the perspective of one person and that discussion of freedom and equality could not be easily hoped for a country until one recognizes the problems faced by all sectors of the society.

`` Peace, And Its Nobleness And Holiness And Honor

June Jordan, a Caribbean-American poet and activist, once explained that poetry in and of itself â€Å"is a political act, because it involves telling the truth.† During World War I, statesmen and politicians propagated the war efforts, asking the men and boys to join the cause and potentially sacrifice their lives for their country. Back in England, war was looked at in the most idealistic light. War was glory. War was honor. War was noble. War was good, and it was right for man to fight. Early in the war, some poets portrayed that rather romanticized version of war. Rupert Brooke spoke about the war’s cleansing abilities in his poem â€Å"Peace† and its nobleness and holiness and honor in â€Å"The Dead.† But many poets chose to send another message to†¦show more content†¦The General’s introductory cry of â€Å"Good-morning; good morning!† upon meeting his troops illustrates an amiable and positive view of war (1). Moving along th e warfront, one soldier, Harry, remarks to fellow soldier, Jack, that their general is â€Å"a cheery old card† (5). The camaraderie, however, is short lived, and these two boys exhibit the human cost of war and of the general’s lack of regard for them, for â€Å"he did for them both by his plan of attack† (7). A week later, â€Å"the soldiers [the general] smiled at are most of ‘em dead† (3). The succinctness and simplicity of the poem echoes the ease with which men died in war. So too, Wilfred Owen, renowned war poet and contemporary and mentee of Siegfried Sassoon, replicates his mentor’s view on the prolific lose of life in war, asking in his poem, â€Å"Anthem of Doomed Youth,† â€Å"What passing-bells for these who die as cattle?† (1). To dispel the propagated glory and honor associated with death in war, in â€Å"Exposure,† Wilfred Owen explores death by the elements, a common and less glorious way men died in battle. Owen famously stated, â€Å"My subject is War, and the pity of War. One such â€Å"pity† that he depicts in his poetry is the dismal death of soldiers by the cold and frost rather than the expected magnificent death of soldiers in man-to-man combat. In â€Å"Exposure,† Owen utilizes the voice of soldiers dying from the cold. â€Å"Our brains ache, in the merciless iced east winds that knive us,† the soldiers